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Adjective: debonaire  ,de-bu'nehr
  1. Having a sophisticated charm
    "a debonaire gentleman";
    - debonair, debonnaire, suave
  2. Having a cheerful, lively, and self-confident air
    "looking debonaire, like a man...diverted by his own wit";
    - chipper, debonair, jaunty

See also: cheerful, refined

Encyclopedia: Debonaire