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Adjective: pouty  paw-tee
  1. Easily irritated or annoyed
    "an incorrigibly pouty young man";
    - cranky, fractious, irritable, nettlesome, peevish, peckish, pettish, petulant, scratchy, testy, tetchy, techy, narky [Brit]
  2. Sullen or moody
    - huffish, sulky
  3. (or a person or mouth) having a pout

See also: ill-natured